Regulatory & Safety Advantages - No Repr. 1B · Combustible (Not Flammable) · No REACH Annex XVII Restriction: Unlike EGEA (CAS 111-15-9) and EGMEA (CAS 110-49-6), DEGEAC (CAS 112-15-2) carries no EU CLP Repr. 1B reproductive toxicant classification and is not subject to REACH Annex XVII Entry 70 consumer restriction. Its flash point of ~107–110°C classifies it as a Combustible Liquid - not Flammable - simplifying storage, workplace safety management, and transport compliance. Confirmed non-HAP under US Clean Air Act.
Non-Repr. · Combustible Liquid · Ultra-High-Boiling Ester Solvent · Coatings / Display Cleaning / Metal Degreasing / Inks
DEGEAC - Diethylene Glycol Monoethyl Ether Acetate
(Carbitol Acetate / DCAC / 2-(2-Ethoxyethoxy)ethyl Acetate / DE Glycol Monoethyl Ether Acetate)
| CAS No. | 112-15-2 |
| EC Number | 203-940-1 |
| IUPAC Name | 2-(2-ethoxyethoxy)ethyl acetate |
| Trade Names | Carbitol Acetate, DCAC, DE Cellosolve Acetate |
| Molecular Formula | C₈H₁₆O₄ (MW = 176.21 g/mol) |
| EU CLP / REACH | ✓ Not Repr. 1B ✓ No SVHC / No CMR ✓ Not REACH Ann. XVII restricted |
| GHS / Transport | Combustible Liquid (FP ~107–110°C) No Class 3 DG shipping requirement |
| US HAP Status | ✓ Not a US EPA HAP · TSCA listed |
| Grade / Purity | ≥ 99.0% · Water ≤0.05% · Acidity ≤0.03% |
What Is DEGEAC (Carbitol Acetate)? Structure & Technical Overview
Diethylene Glycol Monoethyl Ether Acetate (DEGEAC / Carbitol Acetate, CAS 112-15-2) is an ultra-high-boiling ester solvent with molecular formula C₈H₁₆O₄ (MW 176.21 g/mol). Its IUPAC structure - CH₃CH₂–O–CH₂CH₂–O–CH₂CH₂–O–CO–CH₃ - extends the EGEA backbone by one additional ethyleneoxy unit, yielding a diethylene glycol chain that produces dramatically different physical properties: boiling point 213–223°C (vs. 154–160°C for EGEA), flash point ~107–110°C (vs. ~56°C), and - critically - freedom from the EU CLP Repr. 1B reproductive toxicant classification that constrains EGEA and EGMEA in EU-regulated markets.
DEGEAC is produced by direct esterification of diethylene glycol monoethyl ether (DEGEE / Carbitol, CAS 111-90-0) with acetic acid under acid catalysis. The diethylene glycol backbone metabolises differently from the ethylene glycol series - it does not generate the ethoxyacetic acid metabolite responsible for EGEA's Repr. 1B designation at relevant exposure concentrations. This is confirmed by the ECHA substance registration for CAS 112-15-2: no Repr., no SVHC, no CMR classification. DEGEAC is also not subject to REACH Annex XVII Entry 70 - the restriction that limits consumer product use of EGEA and EGMEA in the EU.
The flash point of ~107–110°C places DEGEAC in the Combustible Liquid category under GHS - not Flammable Liquid (threshold <60°C). In practical terms this means no Class 3 DG shipping documentation, no explosion-proof electrical requirements at ambient storage temperature, and the ability to use DEGEAC in heated cleaning baths at 60–90°C without the fire safety infrastructure required for flammable solvents like EGEA.
Physical & Chemical Properties of DEGEAC (Carbitol Acetate)
DEGEAC (Carbitol Acetate) Specifications - Sinolook Commercial Standard
| Specification Item | Standard / Value | Test Method / Significance |
|---|---|---|
| Appearance | Colorless transparent liquid | Visual; no haze, color tint, or particulate |
| Purity (GC) | ≥ 99.0% | GC area normalization; minimizes non-volatile residue after evaporation |
| Water Content | ≤ 0.05% | Karl Fischer titration; prevents mineral deposits on display glass during evaporation |
| Acidity (as AcOH) | ≤ 0.03% | Potentiometric titration; protects ITO electrode coatings and anti-reflection coatings from acid attack |
| Density (d20) | 1.010 ± 0.005 g/cm³ | Digital density meter; identity and batch consistency verification |
| Boiling Point | 213.0–223.0 °C (760 mmHg) | Highest boiling point in the commercial glycol ether acetate series; ultra-slow evaporation |
| Flash Point | ~107–110 °C (closed cup) | Combustible Liquid - not Class 3 Flammable; no DG shipping required for standard temperature transport |
| Refractive Index | ~1.421–1.424 (n20/D) | Refractometer; identity confirmation |
| Viscosity (20°C) | ~2.4 mPa·s | Brookfield; low viscosity enables easy metering and blending at ambient temperature |
| Color (Pt-Co) | ≤ 10 | Colorimeter; water-white - no chromophoric degradation products |
| EU Repr. Classification | Not classified ✓ (no Repr. 1B) | Confirmed by ECHA substance dossier CAS 112-15-2; no Repr. pictogram on SDS |
| Packaging | 200 kg iron drum / 1000 kg IBC tank | Non-DG export packaging (no Class 3 Flammable classification) |
Full COA (GC, KF, acidity, density, RI, Pt-Co, viscosity) with every shipment. SGS / Intertek / BV third-party inspection available on request.
DEGEAC (Carbitol Acetate) Applications
1. Waterborne Coatings - Coalescing Agent & Open-Time Extender
With a boiling point of 213–223°C, DEGEAC is among the slowest-evaporating commercial coalescing agents for waterborne acrylic latex, styrene-acrylic, and PUD coating systems. As a coalescing agent, DEGEAC temporarily plasticises the surface of polymer latex particles during film formation - lowering their glass transition temperature (Tg) sufficiently to allow deformation, coalescence, and fusion into a continuous, defect-free film at ambient application temperatures. Its extended plasticisation window is particularly valuable for cold-substrate application (below 10°C) in exterior architectural coatings, where faster-evaporating coalescing solvents cause film-formation defects before adequate particle fusion occurs.
In premium EU-market waterborne wood coatings - where DEGEAC's non-Repr. status makes it accessible to formulators who cannot use EGEA - its high boiling point provides a coalescence window long enough to achieve complete film formation in high-Tg PUD systems on dense hardwood substrates (oak, beech, bamboo). The result is superior early-coat hardness development, improved intercoat adhesion in multi-coat systems, and lower-defect surface finish vs. faster-evaporating alternatives.
2. Solvent-Borne Coatings & NC Lacquers - Maximum Open-Time Tail Solvent
In solvent-borne NC lacquers, alkyd coatings, and two-pack polyurethane industrial coatings, DEGEAC functions as an ultra-slow tail solvent - the highest-boiling component of the solvent blend that remains in the film longest and controls the final stages of drying and leveling. At 213–223°C, DEGEAC's boiling point is approximately 55–65°C higher than EGEA's - providing a substantially extended flow window in the final drying phase of thick-film industrial coatings applied to complex shapes (pipes, structural steel, marine equipment).
In high-build anti-corrosion coatings for marine and offshore steel structures - where dry-film thickness uniformity over rough blast-cleaned profiles is critical for corrosion protection reliability - DEGEAC's extreme slow evaporation gives the wet film sufficient mobility time to self-level over surface peaks and recesses, improving thickness uniformity and reducing long-term repainting frequency.
3. Electronic Display Cleaning - LCD, OLED & Touchscreen Panels
DEGEAC's combination of purity ≥99.0%, water ≤0.05%, acidity ≤0.03%, near-zero ambient vapor pressure, and non-Repr. status makes it an exceptional cleaning solvent for precision optical surfaces in electronic display manufacturing. In LCD and OLED panel fabrication, DEGEAC removes organic contamination films - light hydrocarbon deposits from cleanroom air, fingerprint oils, lubricant traces from automated assembly equipment - that reduce display contrast and brightness if left on panel surfaces before encapsulation.
Critical cleaning performance requirements met by Sinolook's DEGEAC: complete organic contamination removal at low use concentrations; zero residue after evaporation (low water content and high purity prevent salt or mineral deposits on glass during evaporation); no interaction with polariser films, ITO electrode coatings, optical adhesive layers, or anti-reflection coatings in LCD panel construction. Ultra-low acidity (≤0.03%) prevents acid attack on ITO electrodes and anti-reflection coatings - a critical specification requirement in high-specification display manufacturing.
For touchscreen cover glass - capacitive touch panels using ITO or silver nanowire sensors - DEGEAC's zero ionic residue after evaporation maintains surface resistivity uniformity of the transparent electrode layer critical for touch sensitivity calibration. Its non-Repr. profile also simplifies chemical management in cleanroom environments where Repr. 1B classified solvents require reproductive health risk assessments and enhanced worker monitoring protocols.
4. Industrial Metal Cleaning - Non-Flammable Hot-Process Degreasing
DEGEAC's flash point of ~107–110°C enables its use in heated immersion cleaning tanks operating at 60–90°C - a process temperature range incompatible with flammable solvents like EGEA (flash point ~56°C) under OSHA 1910.106 and equivalent international fire safety standards. DEGEAC can be used in heated cleaning bath systems without triggering flammable liquid facility classification requirements, enabling simpler and less costly heated cleaning system design.
In precision metal component cleaning for aerospace, medical device, and defence manufacturing - where zero residue is required before anodising, electroplating, thermal spray coating, or adhesive bonding - DEGEAC's high volatility at 50–80°C combined with non-ionic composition ensures residue-free surfaces after vacuum-assisted or warm-air drying. Compatible with aluminium alloys, titanium, stainless steel, and engineering polymer substrates.
5. Printing Inks, Leather Finishing & Chemical Synthesis
Printing inks: DEGEAC's boiling point of 213–223°C makes it the slowest-evaporating commercial glycol ether acetate retarder for gravure and screen printing ink formulations. In high-speed rotogravure on metallic foil substrates - where thermal conductivity accelerates ink drying - DEGEAC's extreme retention in the liquid ink phase prevents premature drying on fine-cell cylinders (below 25 μm cell depth) at press speeds above 400 m/min. In functional screen printing inks (conductive silver pastes, resistive/dielectric inks for membrane switches) DEGEAC maintains ink rheology through extended squeegee stroke times, preventing viscosity increase and screen blocking in fine-line conductor patterns.
Leather finishing: High boiling point ensures adequate penetration of PU finishing systems into leather grain structure before surface film formation, achieving adhesion and mechanical flexibility requirements for footwear, automotive interior leather, and upholstery. Non-Repr. status simplifies occupational health management in leather finishing operations.
Chemical synthesis: DEGEAC's boiling point (213–223°C), thermal stability above 200°C, and non-Repr. status make it a preferred reaction medium for pharmaceutical API purification, agrochemical intermediate synthesis, and fine chemical processes requiring a high-boiling polar ester solvent where Repr. 1B solvents cannot be used.
DEGEAC vs. EGEA vs. DPGMEA - High-Boiling Ester Solvent Selection Guide
DEGEAC is most frequently evaluated against EGEA as a regulatory upgrade, and against DPGMEA (Dipropylene Glycol Monomethyl Ether Acetate) as a P-series non-Repr. alternative. Sinolook supplies all three. The comparison below maps the key selection dimensions for coating, cleaning, and ink formulators.
| Property | EGEA CAS 111-15-9 |
DEGEAC (Carbitol Ac.) CAS 112-15-2 |
DPGMEA CAS 88917-22-0 |
|---|---|---|---|
| Common Name | Cellosolve Acetate | Carbitol Acetate / DCAC | Dowanol DPMA |
| Series | E-series (mono-EG) | E-series (di-EG) | P-series (di-PG) |
| Mol. Formula / MW | C₆H₁₂O₃ / 132.16 | C₈H₁₆O₄ / 176.21 | C₈H₁₆O₄ / 176.21 |
| Boiling Point (°C) | 154–160 | 213–223 ↑ Highest | ~190–200 |
| Flash Point (°C) | ~56 Flammable ⚠ | ~107–110 Combustible ✓ | ~84 Combustible ✓ |
| Evaporation Rate | Moderate | Very Slow ↑ Slowest | Slow |
| EU CLP Repr. Class. | Repr. 1B ⚠ | Not classified ✓ | Not classified ✓ |
| REACH Annex XVII | Restricted ⚠ | Not restricted ✓ | Not restricted ✓ |
| DG Transport Class | Class 3, PG III ⚠ | No Class 3 DG ✓ | No Class 3 DG ✓ |
| US HAP Status | Not listed ✓ | Not listed ✓ | Not listed ✓ |
| Key Positioning | Moderate bp; Repr. 1B restricted; lower cost | Highest bp; non-Repr.; combustible; heated-bath compatible | P-series; non-Repr.; ~20°C lower bp than DEGEAC |
DEGEAC Regulatory Status - The Non-Repr. Advantage in Detail
Storage, Stability & Safety Handling
Storage Requirements
Store at 5–40°C in sealed metal drums, away from heat sources above 100°C, open flames, strong acids, and oxidizers. No explosion-proof electrical requirements at standard ambient storage temperature. Keep containers tightly sealed - DEGEAC hydrolyses slowly to DEGEE + acetic acid in the presence of moisture and acid/base catalysts; moisture exclusion maintains specification compliance and prevents acidity increase.
Compatible materials: stainless steel (304/316), carbon steel, HDPE, aluminium. Segregate from strong acids (hydrolysis catalysts), strong bases, peroxides, and oxidizers. Stack maximum 3 layers for 200 kg drums.
Shelf life: 24 months from manufacture date under recommended conditions. Retest purity (GC), acid value, and water content before use if stored longer than 12 months or if drum seal integrity is uncertain.
PPE & Handling (SDS Summary)
GHS hazards: Combustible Liquid (H227, flash point 107–110°C), Eye Irritant 2 (H319), Skin Irritant 2 (H315). No Repr. 1B; no SVHC. No reproductive health restrictions on worker categories.
Gloves: Nitrile (≥0.15 mm) for incidental contact; butyl rubber for extended use. Eye protection: Safety goggles for splash risk during transfer; face shield for bulk pumping. Near-zero ambient vapor pressure: inhalation risk is low in cold-process handling.
Heated processing (>60°C): Local exhaust ventilation (LEV) recommended as vapor generation increases with temperature. Refer to GESTIS database (CAS 112-15-2) for OEL data by jurisdiction.
Spill: Use inert absorbent (vermiculite, dry sand). Avoid ignition sources if spill is heated. Dispose as industrial chemical waste per local regulations. Full GHS-compliant SDS: sales@sinolookchem.com.
Frequently Asked Questions about DEGEAC / Carbitol Acetate
Q: What is the difference between DEGEAC and EGEA, and when should I choose one over the other?
EGEA (CAS 111-15-9) uses a single ethylene glycol backbone; DEGEAC (CAS 112-15-2) adds one additional ethyleneoxy unit to create a diethylene glycol chain. This structural difference produces three decisive property changes: DEGEAC's boiling point (213–223°C) is ~60°C higher than EGEA's (154–160°C); its flash point (~107°C) is ~50°C higher - changing GHS classification from Flammable to Combustible Liquid; and DEGEAC carries no Repr. 1B classification, unlike EGEA. Choose DEGEAC when: maximum open time and leveling is the priority; a non-flammable process solvent is required (heated baths at 60–90°C); EU regulatory compliance without Repr. 1B constraints is needed; or display-grade cleaning purity at near-zero ambient vapor pressure is required. Choose EGEA when a faster-drying solvent is needed and regulatory constraints have been addressed for the specific application and market.
Q: Is DEGEAC considered a VOC under EU regulations?
Yes. DEGEAC's boiling point of 213–223°C falls below the EU Paints Directive 2004/42/EC 250°C VOC threshold - it is therefore counted as a VOC in EU architectural and decorative coating products subject to the Directive's VOC limit categories. Formulators using DEGEAC in EU Ecolabel, low-VOC, or zero-VOC labelled architectural coatings must include its VOC contribution in declared VOC content. For reference, solvents with boiling points above 250°C (e.g., DEGHE CAS 112-59-4, bp ~260°C) may qualify for VOC-exempt treatment. Sinolook provides boiling point and molecular weight data to support EU VOC compliance calculations for all coating customers.
Q: Can DEGEAC replace EGEA weight-for-weight in NC lacquer formulations?
A direct weight-for-weight substitution is a reasonable starting point for reformulation trials, but adjustments will typically be needed. DEGEAC's higher MW (176 vs 132 g/mol) and significantly slower evaporation rate mean that substituting at equivalent weight loading will substantially extend dry time - which may cause unacceptably long dust-free times in high-throughput production lines. Formulators should typically use DEGEAC at approximately 70–80% of the EGEA weight (volume-corrected) and compensate with faster mid-boiling co-solvents (ethyl acetate, MEK, n-butyl acetate) to recover the overall drying profile while retaining DEGEAC's contribution to final leveling quality. Sinolook provides reformulation guidance including comparative solubility parameter and evaporation profile analysis - contact our technical team.
Q: What purity grade of DEGEAC is required for LCD and OLED display panel cleaning?
Display panel cleaning typically requires: purity ≥99.0% by GC (minimises non-volatile residue after evaporation), water ≤0.05% (prevents mineral/ionic deposits on glass during evaporation), acidity ≤0.03% as AcOH (prevents acid attack on ITO electrode or anti-reflection coatings), and color ≤10 Pt-Co (absence of coloured degradation products that could stain optical surfaces). Sinolook's standard DEGEAC specification meets all these requirements. For ultra-high-specification OLED applications requiring non-volatile residue below 1 ppm, higher-purity DEGEAC (≥99.5%) with additional trace metal analysis may be requested - contact our team to discuss availability and analytical options.
Q: What is DEGEAC's shelf life, and how should it be tested before use after extended storage?
Recommended shelf life is 24 months from manufacture date in original sealed packaging at 5–40°C. The primary degradation mechanism is hydrolysis - catalysed by moisture and acidic/alkaline impurities - generating DEGEE (Carbitol) + acetic acid and raising acid value. Before using stock stored longer than 12 months, or in any application where specification compliance is critical, retest: purity by GC (detects DEGEE formation), acid value as AcOH (detects hydrolysis onset), and water content by Karl Fischer. Drums with damaged seals or external moisture contamination should be retested regardless of storage duration. Sinolook provides COAs with test dates so customers can track product age and plan retesting schedules.
Authoritative Technical & Regulatory References
ECHA substance page confirming EU REACH registration, absence of Repr. 1B and SVHC classification, and registered industrial uses for Carbitol Acetate / 2-(2-ethoxyethoxy)ethyl acetate.
NCBI PubChem compound record: IUPAC name, molecular structure, physicochemical properties, and GHS hazard data for DEGEAC (CAS 112-15-2).
EPA CompTox Chemicals Dashboard: TSCA inventory status, non-HAP classification confirmation, physicochemical property data for DEGEAC.
IFA GESTIS substance database for CAS 112-15-2: occupational exposure limits, toxicological summary, and workplace safety measures for DEGEAC handling.
DEGEAC's boiling point (213–223°C) is below the 250°C VOC threshold - it counts as a VOC in EU architectural coating VOC calculations. Relevant for EU Ecolabel and low-VOC formulation compliance.
ASTM method for VOC content calculation in paints and coatings. DEGEAC's boiling point and molecular weight are relevant parameters for calculating its VOC contribution in ASTM D3960-compliant industrial coating formulations.
Buy DEGEAC / Carbitol Acetate from China · Non-Repr. · Combustible · Full Regulatory Package
Request DEGEAC Price, Sample & Non-Repr. Regulatory Documentation
Sinolook supplies Diethylene Glycol Monoethyl Ether Acetate (DEGEAC / Carbitol Acetate, CAS 112-15-2) at ≥99.0% purity, water ≤0.05%, acidity ≤0.03%, with full COA, GHS-compliant SDS (no Repr. 1B pictogram), REACH non-Repr. confirmation letter, REACH Annex XVII Entry 70 non-applicability letter, and non-HAP declaration. MOQ 1 MT; qualification samples from 0.5 kg. Standard lead time 10–15 business days. Response within 24 hours.
Related products: EGEA (Ethylene Glycol Monoethyl Ether Acetate) · EGMEA (Ethylene Glycol Monomethyl Ether Acetate) · DEGEE (Diethylene Glycol Monoethyl Ether / Carbitol) · DPGMEA (Dipropylene Glycol Monomethyl Ether Acetate) · PGMEA (Propylene Glycol Monomethyl Ether Acetate) · Diethylene Glycol Monobutyl Ether Acetate
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