EU CLP / REACH Regulatory Notice: EGEA (CAS 111-15-9) is classified as Repr. 1B (H360D - May damage the unborn child) under EU CLP Regulation (EC) No 1272/2008, and is restricted in consumer products under REACH Annex XVII Entry 70. Industrial and professional occupational use is permitted under mandatory exposure controls. Sinolook provides full CLP-compliant SDS, REACH Annex XVII status confirmation, and PGMEA transition support with every shipment. Buyers are responsible for verifying compliance with applicable national regulations.
E-Series Glycol Ether Acetate · Slow-Evaporation Ester Solvent · NC Coatings / Leather / Inks / Electronics
EGEA - Ethylene Glycol Monoethyl Ether Acetate
(Cellosolve Acetate / CAC / 2-Ethoxyethyl Acetate / EG Monoethyl Ether Acetate)
| CAS No. | 111-15-9 |
| EC Number | 203-839-2 |
| IUPAC Name | 2-ethoxyethyl acetate |
| Trade Names | Cellosolve Acetate, CAC, EGEAC, EAC |
| Synonyms | EGEA, 2-ethoxyethyl acetate, ethylene glycol monoethyl ether acetate, ethyl cellosolve acetate, glycol monoethyl ether acetate |
| Molecular Formula | C₆H₁₂O₃ (MW = 132.16 g/mol) |
| EU CLP / REACH | ⚠ Repr. 1B (H360D) REACH Annex XVII Entry 70 |
| US HAP Status | ✓ Not a US EPA HAP TSCA inventory listed · non-HAP declaration available |
| Grade / Purity | ≥ 99.5% · Water ≤0.05% · Acidity ≤0.02% |
What Is EGEA (Cellosolve Acetate)? Structure & Technical Overview
Ethylene Glycol Monoethyl Ether Acetate (EGEA / Cellosolve Acetate, CAS 111-15-9) - also known as 2-ethoxyethyl acetate - is a high-solvency ester solvent with molecular formula C₆H₁₂O₃ (MW 132.16 g/mol). Its structure is CH₃CH₂–O–CH₂CH₂–O–CO–CH₃: an ethylene glycol backbone with an ethyl ether at one end and an acetate ester at the other. This dual ether–ester functionality delivers broad solvency for nitrocellulose, alkyd, vinyl, polyurethane, and cellulosic resin systems - combined with a controlled moderate evaporation rate (bp 154–160°C, ~5–6× slower than n-butyl acetate) that makes it particularly valuable in coatings and inks where extended flow and leveling time is critical.
EGEA is produced by direct esterification of ethylene glycol monoethyl ether (EGEE, CAS 110-80-5) with acetic acid under acid catalysis. Compared to its methyl homolog EGMEA (bp 143–145°C), EGEA's higher boiling point (154–160°C) and ethyl ether group give it a marginally slower evaporation rate - a meaningful difference in large-panel furniture lacquer and automotive refinish applications where additional leveling time prevents orange peel and surface texture defects. Sinolook supplies EGEA to the tightest commercial specifications in the category: water content ≤0.05% and acidity ≤0.02% - both significantly tighter than our EGMEA specification, reflecting EGEA's requirements in electronic cleaning and moisture-sensitive coating systems.
Buyers must clearly understand EGEA's regulatory profile: it is classified as Repr. 1B (H360D) under EU CLP, arising from metabolic conversion to ethoxyacetic acid - a reproductive toxicant analogous to EGMEA's methoxyacetic acid metabolite. Consumer product use is restricted under REACH Annex XVII Entry 70. Industrial occupational use is permitted with mandatory exposure controls. For new EU-market formulation development, PGMEA (CAS 108-65-6) is the recommended regulatory substitute - Sinolook supplies PGMEA and provides full transition support.
Physical & Chemical Properties of EGEA (2-Ethoxyethyl Acetate)
EGEA (Cellosolve Acetate) Specifications - Sinolook Commercial Standard
| Specification Item | Standard / Value | Test Method / Significance |
|---|---|---|
| Appearance | Colorless transparent liquid | Visual; no haze, precipitate, or color tint |
| Purity (GC) | ≥ 99.5% | GC area normalization; every batch |
| Water Content | ≤ 0.05% | Karl Fischer titration; prevents hydrolysis & moisture-sensitive system failures |
| Acidity (as AcOH) | ≤ 0.02% | Potentiometric titration; critical for electronics & base-sensitive coatings |
| Density (d20) | 0.973 ± 0.005 g/cm³ | Digital density meter; identity & batch consistency confirmation |
| Boiling Point | 154.0–160.0 °C (760 mmHg) | ~5–6× slower evaporation vs n-butyl acetate |
| Flash Point | ~56 °C (closed cup) | Class 3 Flammable Liquid; UN 3271, PG III for transport |
| Refractive Index | 1.403–1.406 (n20/D) | Refractometer; identity and purity confirmation |
| Viscosity (20°C) | ~1.3 mPa·s | Brookfield; easy pipeline blending and metering |
| Color (Pt-Co) | ≤ 10 | Colorimeter; water-white clarity |
| Packaging | 200 kg iron drum / 1000 kg IBC tank | DG Class 3 UN-approved export packaging |
Full COA (GC, KF, acidity, density, RI, Pt-Co, viscosity) with every shipment. Third-party inspection (SGS/Intertek/BV) available on request.
EGEA (Cellosolve Acetate) Uses & Applications
1. Nitrocellulose Lacquers & Alkyd Coatings - Extended Leveling Solvent
EGEA is a flagship solvent in nitrocellulose (NC) lacquer systems, filling the role of slow-evaporation primary or tail solvent for furniture coatings, automotive refinishing, and leather topcoats. Its boiling point of 154–160°C - approximately 10–15°C higher than EGMEA - extends the flow and leveling window after spray application, giving the wet film additional time to self-level and release entrapped air before surface gelation. In automated high-volume furniture spray lines, this additional leveling time directly reduces defect rates (orange peel, blush, cratering) that generate rework costs on large flat panels and complex edge profiles.
EGEA dissolves NC grades across the full viscosity range (RS-1/4 to RS-25) at high solids content, reducing overall solvent loading in low-VOC NC lacquer formulations. Its compatibility with alkyd co-resins, plasticizers (phthalates, citrates), and pigment dispersions makes it versatile across wood, furniture, and automotive refinish product lines.
In markets outside the EU - particularly Asia, the Middle East, and Latin America where NC coatings remain dominant for furniture and leather finishing - EGEA continues to be widely specified under locally applicable occupational and environmental regulations. Sinolook serves these markets with full local-format documentation support.
2. Gravure & Screen Printing Inks - Slow-Evaporation Retarder
EGEA's high solvency for polyurethane, vinyl chloride/acetate copolymer, and cellulosic ink binder systems combined with its slow evaporation profile makes it an effective retarder and co-solvent in gravure inks for paper, foil, and rigid packaging substrates, and in screen printing inks for industrial decoration, membrane switch graphics, and metallic panel printing. Adding EGEA prevents premature solvent flash-off in the ink train, maintaining viscosity and preventing mesh-blocking during production stoppages.
EGEA's compatibility with both polar and non-polar pigment dispersant systems enables it to function across transparent and opaque ink formulations without introducing compatibility or stability problems. Its low acidity specification (≤0.02%) protects base-sensitive pigments from acid-induced flocculation and color shift in aged ink concentrates - a quality advantage over lower-specification EGEA grades available in the market.
3. Leather Finishing - PU & NC Topcoats for Footwear & Automotive Leather
The leather finishing industry has historically used EGEA as a primary solvent for polyurethane finishing systems and NC-based topcoats applied to full-grain and split leather for footwear, handbags, automotive interior leather, and upholstery. EGEA controls the drying rate of PU finishing systems - allowing sufficient penetration into the leather grain structure before surface film formation - achieving the adhesion and mechanical flexibility that leather service performance demands across repeated flexing, abrasion, UV exposure, and thermal cycling.
In premium automotive interior leather finishing - where coatings must withstand occupant wear, thermal cycling from −30°C to +80°C, and UV exposure over multi-year service life - EGEA's compatibility with flexible PU resin systems contributes to defect-free finishing film formation on complex three-dimensional parts. For leather manufacturers in markets where EGEA's regulatory status permits use in occupational settings, it remains a technically competitive solvent for established finishing formulations.
4. Electronic Component Cleaning - Ultra-Low Moisture & Acidity
EGEA's tightest-in-category specifications - purity ≥99.5%, water ≤0.05%, acidity ≤0.02%, color ≤10 Pt-Co - make it a high-purity cleaning solvent for electronic component applications requiring residue-free evaporation. It provides effective dissolution of rosin-based flux resin binders and activator salts from wave-soldered and reflow-soldered PCB assemblies, cleaning dense complex board geometries with bridged components and via-in-pad structures where aqueous cleaning is impractical.
For precision electronic components - optical pickups, MEMS sensors, micro-electromechanical switch assemblies, and precision metal contacts - EGEA's ultra-low acidity (≤0.02%) prevents acid corrosion of sensitive metal contact surfaces, while its low residue after evaporation avoids contamination of insulating surfaces. Compatibility with FR4, polyimide PCB substrates and standard solder mask formulations is confirmed at Sinolook's specification levels.
5. Industrial Coatings, Adhesives & Chemical Synthesis
In two-component polyurethane and epoxy industrial coatings for metal, concrete, and composite substrates, EGEA functions as a co-solvent and viscosity modifier that extends pot life and allows adequate film spreading over complex metal geometries before gellation. Its compatibility with both the polyol and isocyanate components of 2K PU systems without causing premature phase separation is a key formulation requirement met by EGEA's combined ether-ester solvency profile.
As a chemical synthesis solvent, EGEA's boiling point (154–160°C), thermal stability, and compatibility with a broad range of nucleophiles and electrophiles make it suitable as a reaction medium in pharmaceutical API synthesis, agrochemical production, and specialty fine chemical processes requiring a polar high-boiling ester solvent. It is also used as an extraction and recrystallization solvent for polar APIs.
In textile printing, EGEA acts as a penetrant and leveling agent in reactive, disperse, and vat dye printing systems, improving dye penetration depth and color uniformity on cotton, polyester, and blended fabric substrates.
EGEA vs EGMEA vs PGMEA - Glycol Ether Acetate Solvent Selection Guide
EGEA is most frequently evaluated alongside its methyl homolog EGMEA and the regulatory substitute PGMEA. Sinolook supplies all three - the comparison below maps technical and regulatory dimensions relevant to coating and ink formulators selecting between the glycol ether acetate series.
| Property | EGMEA CAS 110-49-6 |
EGEA (Cellosolve Ac.) CAS 111-15-9 |
PGMEA (PMA) CAS 108-65-6 |
|---|---|---|---|
| Common Name | Methyl Cellosolve Ac. | Cellosolve Acetate / CAC | PMA / Dowanol PMA |
| Mol. Formula | C₅H₁₀O₃ | C₆H₁₂O₃ | C₆H₁₂O₃ |
| Boiling Point (°C) | 143–145 | 154–160 ↑ Slowest | 146–148 |
| Flash Point (°C) | ~49 | ~56 ↑ Safest | ~47 |
| Density (g/cm³) | 1.005–1.010 | 0.973 ± 0.005 | 0.964–0.968 |
| Evaporation Rate (vs nBuAc=1) | ~0.22–0.26 | ~0.18–0.22 (slowest) | ~0.25 |
| NC Solvency | Excellent | Excellent | Very Good |
| Water Content Spec. | ≤ 0.10% | ≤ 0.05% ↑ Tightest | ≤ 0.05% |
| Acidity Spec. | ≤ 0.10% | ≤ 0.02% ↑ Tightest | ≤ 0.02% |
| EU CLP Repr. Class. | Repr. 1B ⚠ | Repr. 1B ⚠ | Not classified ✓ |
| REACH Annex XVII | Restricted ⚠ | Restricted ⚠ | No restriction ✓ |
| US HAP Status | Not listed ✓ | Not listed ✓ | Not listed ✓ |
EGEA Regulatory Status - EU CLP, REACH & Global Markets
Storage, Stability & Safety Handling
Storage Requirements
Store at 5–30°C in sealed metal drums, away from heat, open flames, UV light, strong acids, and oxidizers. Flash point 56°C requires explosion-proof electrical equipment in storage and handling areas. EGEA hydrolyses to EGEE + acetic acid in the presence of moisture and acid/base catalysts - maintaining sealed drums and strict moisture exclusion is the primary quality preservation measure.
Compatible storage materials: stainless steel (304/316), carbon steel, HDPE. Avoid copper, brass, and galvanized steel for extended contact. Segregate from areas occupied by pregnant workers. Shelf life: 12 months; retest water content and acidity before use if stored >6 months.
Hydrolysis & Stability
EGEA's primary degradation mechanism is hydrolysis (EGEA + H₂O → EGEE + acetic acid), accelerated by moisture and acid/base impurities. This increases acidity, reduces purity, and generates a sharp acetic acid odor. The strict ≤0.05% water spec and sealed drum storage are the critical controls.
PPE & Exposure Controls (SDS Summary)
GHS classification: Repr. 1B (H360D), Flammable Liquid Category 3 (H226), Skin Irritation Category 2, Eye Irritation Category 2. EGEA absorbs through skin - dermal exposure is a significant route of systemic uptake.
PPE: Nitrile gloves (≥0.3 mm) or butyl rubber, safety goggles, protective clothing. Local exhaust ventilation (LEV) as primary engineering control to maintain below applicable national OEL. Refer to GESTIS database (CAS 111-15-9) for OEL data by jurisdiction.
Health surveillance: Implement risk assessment and health monitoring for workers of childbearing potential. Pregnant workers must be excluded from EGEA handling areas.
Spill: Eliminate ignition sources, ventilate area. Use inert absorbent (sand, vermiculite). Dispose as flammable/hazardous waste per local regulations. Full CLP-compliant SDS: sales@sinolookchem.com.
Frequently Asked Questions about EGEA / Cellosolve Acetate
Q: What does "CAC" stand for, and is it the same as EGEA?
CAC is a legacy trade abbreviation for Cellosolve Acetate, referring specifically to Ethylene Glycol Monoethyl Ether Acetate (CAS 111-15-9). Historically sold under the Cellosolve brand by Union Carbide, "Cellosolve" denoted the ethylene glycol monoethyl ether (EGEE) base compound and "Cellosolve Acetate" its acetate ester. In modern procurement, CAC, EGEA, EGEAC, and EAC all refer unambiguously to CAS 111-15-9. Always verify using CAS 111-15-9 and EC 203-839-2 to avoid confusion with EGMEA (CAS 110-49-6), which differs by one methylene group on the ether chain.
Q: How does EGEA's evaporation rate compare to other industrial solvents?
EGEA's evaporation rate relative to n-butyl acetate (nBuAc = 1.0) is approximately 0.18–0.22, meaning it evaporates 5–6× more slowly than nBuAc. This places it in the "slow" evaporation category - slower than EGMEA (~0.22–0.26), slower than PGMEA (~0.25), and approximately 5–6× slower than ethyl acetate or MEK. In practical coating terms, EGEA's slow evaporation profile is most valuable in high-film-build spray applications on large flat panels and complex 3D geometries, in brush-applied coatings where application time extends over minutes, and as a "tail solvent" in multi-solvent NC lacquer blends designed to control flow and drying characteristics from initial spray through final film hardening.
Q: Why is EGEA's water content specification tighter than EGMEA's?
Sinolook's EGEA specification holds water content at ≤0.05% - half the ≤0.10% limit applied to EGMEA. Two factors drive this: (1) EGEA's primary use in electronic component cleaning and precision electronic coating systems demands extremely low moisture to prevent metal contact surface contamination and to avoid interfering with base-sensitive encapsulant and conformal coating curing chemistry; (2) EGEA's slightly longer alkyl chain (ethyl vs methyl) increases its hydrolysis susceptibility relative to EGMEA under equivalent moisture conditions - stricter moisture control is needed to maintain specification stability over the stated 12-month shelf life. This requires more stringent production dehydration and packaging, which is reflected in EGEA's slightly higher typical market price compared to EGMEA.
Q: Is EGEA a non-HAP solvent for US EPA air emission compliance purposes?
Yes - EGEA (CAS 111-15-9) is not listed as a Hazardous Air Pollutant (HAP) under Section 112(b) of the US Clean Air Act. This is confirmed by the EPA CompTox Chemicals Dashboard. EGEA use in US manufacturing facilities does not trigger HAP air emission monitoring, reporting, or control obligations under National Emission Standards for Hazardous Air Pollutants (NESHAP) - a meaningful advantage for coating and ink manufacturers managing facility-level HAP emission inventories under MACT standards. Note that standard US OSHA HazCom 2012 occupational exposure requirements apply regardless of HAP status. Sinolook provides non-HAP declaration letters for US customers on request.
Q: What is the practical process for transitioning from EGEA to PGMEA in a coating formulation?
The recommended transition process: (1) request a PGMEA qualification sample from Sinolook and prepare a test batch replacing EGEA weight-for-weight; (2) evaluate the test formulation for viscosity (PGMEA's lower density ~0.966 vs EGEA's ~0.973 may require minor adjustment), drying rate (PGMEA's slightly lower bp ~147°C may give marginally faster drying - assess whether open time remains adequate), and film quality (flow, leveling, gloss - expected to be equivalent in most NC and PU systems); (3) if adhesion or resin solvency differences appear, contact Sinolook's technical team for solubility parameter guidance and co-solvent adjustment recommendations; (4) validate the reformulated product against your full quality specification suite before commercial transition. Sinolook provides comparative solubility data, qualification samples, and one-to-one technical support for EGEA→PGMEA transitions.
Authoritative Technical & Regulatory References
CLP Repr. 1B classification, REACH Annex XVII Entry 70 restriction details, registered industrial uses, and regulatory obligations for 2-ethoxyethyl acetate / Cellosolve Acetate.
NCBI PubChem compound record: IUPAC name, molecular structure, physicochemical data, GHS hazard classifications, and spectral data for EGEA (CAS 111-15-9).
EPA CompTox dashboard: TSCA inventory status, non-HAP classification confirmation, physicochemical property data, and environmental fate information for EGEA.
Consolidated REACH Regulation Annex XVII - Entry 70 restricting E-series glycol ethers including EGEA in consumer products above specified concentration limits.
IFA GESTIS substance database entry for CAS 111-15-9: occupational exposure limits (OEL), toxicological summary, and engineering control recommendations for EGEA.
Buy EGEA / Cellosolve Acetate from China · Non-HAP · Full Regulatory Documentation
Request EGEA Price, Sample & Regulatory Documentation
Sinolook supplies Ethylene Glycol Monoethyl Ether Acetate (EGEA / Cellosolve Acetate, CAS 111-15-9) at ≥99.5% purity, water ≤0.05%, acidity ≤0.02% - the tightest commercial specifications in the glycol ether acetate category. Full CLP-compliant SDS, REACH Annex XVII status letter, non-HAP declaration, and DG transport documentation included. We also supply PGMEA for regulatory transition projects. Response within 24 hours.
Related products: PGMEA (Propylene Glycol Monomethyl Ether Acetate) · EGMEA (Ethylene Glycol Monomethyl Ether Acetate) · EGEE (Ethylene Glycol Monoethyl Ether) · Butyl Cellosolve Acetate · Diethylene Glycol Monoethyl Ether Acetate · PGME (Propylene Glycol Monomethyl Ether)
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