Non-Phthalate Trimellitate · No CMR · No REACH SVHC · No Annex XIV/XVII · Non-HAP · RoHS Compliant · IMDS Phthalate-Free: TM810 (CAS 68515-42-4) is a trimellitate ester - structurally unrelated to phthalates. Not classified as Repr. 1B, Carc., or Muta. under EU CLP 1272/2008. Not on REACH SVHC Candidate List. Not subject to the EU phthalate SVHC/Annex XVII restriction framework (DEHP, DBP, BBP, DIBP framework does not apply to trimellitates). Fully compliant with EU RoHS 2011/65/EU including 2019 phthalate amendments. Flash point ≥240°C (actual 252°C) - Combustible Liquid Class III-B. Volume resistivity ≥5×10¹¹ Ω·cm validated for IEC 60811 cable insulation. Full compliance documentation with every shipment.
Mixed C8/C10 Trimellitate Ester · 105°C Cable Plasticiser · Non-Phthalate · Pour Point −46°C
TM810 - Tri(octyl, decyl) Trimellitate
(TIOTM / Trialkyl Trimellitate C8/C10 / Mixed Octyl Decyl Trimellitate / Tri(n-octyl, n-decyl) Trimellitate)
| CAS No. | 68515-42-4 (correct for TM810 - not CAS 3319-31-1, which is TOTM) |
| EC Number | 271-090-9 |
| Composition | Trimellitate ester of mixed n-octanol (C8) + n-decanol (C10) with TMA · statistical mixture of tri-C8, tri-C10, and four mixed di/mono isomers |
| Average MW | ~570 g/mol average (range 529–613 g/mol across C8/C10 isomers; higher than TOTM ~547) |
| EU CLP / REACH | ✓ No CMR ✓ No SVHC ✓ Non-Phthalate ✓ RoHS Compliant |
| Key Cable Specs | Pour Point ≤−40°C (actual −46°C) Volatile Loss ≤0.10% @ 130°C/3h Vol. Resistivity ≥5×10¹¹ Ω·cm |
| US HAP / TSCA | ✓ Non-HAP ✓ TSCA listed |
What Is TM810? Mixed C8/C10 Trimellitate for 105°C Cables, Automotive PVC & Medical Devices
Tri(octyl, decyl) trimellitate (TM810, CAS 68515-42-4) is a high-performance mixed-alcohol trimellitate ester plasticiser and synthetic lubricant base oil produced by esterification of trimellitic anhydride (TMA) with a blend of n-octanol (C8) and n-decanol (C10) straight-chain primary alcohols. The trade name directly encodes the composition: '8' for the n-octanol component, '10' for the n-decanol component. The resulting product is a statistical mixture of six trimellitate isomers (tri-C8, tri-C10, and four mixed di/mono substitution variants), with an average molecular weight of approximately 570 g/mol and a narrow, reproducible property profile controlled by the C8:C10 inlet alcohol ratio (~50:50 mole fraction).
TM810's mixed C8/C10 linear alcohol architecture delivers three cumulative advantages: lower pour point than TOTM at −46°C (the C10 linear chain's greater conformational mobility reduces crystallisation tendency vs TOTM's branched 2-ethylhexyl chain), lower volatile loss than TOTM at 130°C/3h (0.08% actual) (higher average MW reducing volatility vs single-C8 trimellitate), and volume resistivity ≥5×10¹¹ Ω·cm meeting IEC 60811 electrical insulation requirements for 105°C-rated PVC cable compounds. TMA raw material is 90% domestically supplied in China, directly supporting competitive TM810 pricing.
Physical & Electrical Properties of TM810
TM810 Full Specification - Multi-Standard COA (ASTM D1045 / D92 / D97 / Karl Fischer)
| Item | Method | Specification | Typical | Note |
|---|---|---|---|---|
| Appearance (25°C) | Visual | Colorless–Pale Yellow Transparent Liquid | Colorless | No haze, turbidity or particulate |
| Ester Content | ASTM D1045 | ≥99.0% | 99.5% | Near-complete 3-site esterification; consistent plasticiser efficiency |
| Acid Value | ASTM D1045 | ≤0.10 mg KOH/g | 0.05 | Prevents PVC heat stabiliser consumption during processing |
| Moisture | Karl Fischer | ≤0.10% | 0.06% | Critical for hydrolytic stability; excess moisture increases acid value in storage |
| Color (Pt-Co) | ASTM D1045 | ≤50 | 30 | Medical grade: Pt-Co ≤30 + heavy metals (Pb, Cd, Hg, Cr) on request |
| Specific Gravity (27°C) | ASTM D1045 | 0.974–0.980 | 0.977 | Narrow range confirms consistent C8/C10 isomeric composition batch-to-batch |
| Refractive Index (27°C) | ASTM D1045 | 1.4855–1.4865 | 1.4860 | Structural fingerprint; confirms correct mixed trimellitate composition |
| Viscosity (20°C) | Rotational | 490–505 cP | 497 cP | High-viscosity liquid; trace heating may assist cold-weather bulk transfers |
| Flash Point (COC) | ASTM D92 | ≥240°C | 252°C | Combustible Liquid Class III-B; no explosion-proof storage; no vapour at ambient |
| Pour Point | ASTM D97 | ≤−40°C | −46°C | 7°C lower than TOTM (~−39°C); decisive for −40°C cold-bend cable qualification |
| Volatile Loss (130°C/3h) | ASTM D1045 | ≤0.10% | 0.08% | Lower than TOTM (~0.15–0.20%); validates 105°C service life + autoclave sterilisation |
| Volume Resistivity | KLJTM/IEC 60811 | ≥5×10¹¹ Ω·cm | 7.0×10¹¹ Ω·cm | Critical for medium-voltage cable insulation (6 kV, 10 kV); low-resistivity impurities cause dielectric failure |
| Packaging | - | 200 kg sealed metal drum · 1000 kg IBC | - | Combustible Liquid Class III-B; no Class 3 Flammable Liquid DG restrictions |
TM810 Applications
1. 105°C Grade Heat-Resistant PVC Cable - Wire & Cable Industry
The wire and cable industry is TM810's largest global application. IEC 60502 and UL 44 require plasticisers combining low volatility (preventing embrittlement during 20+ year cable service life) and low-temperature flexibility (maintaining performance during cold-climate cable installation). TM810 satisfies both simultaneously: volatile loss ≤0.10% at 130°C/3h ensures plasticiser retention at 105°C service (130°C is the corresponding accelerated aging test temperature), while pour point −46°C maintains flexibility at the −40°C cold-bend temperature required for IEC 60502 qualification - meeting a specification that TOTM (~−39°C) only barely achieves.
The volume resistivity requirement (≥5×10¹¹ Ω·cm, actual 7.0×10¹¹) is a critical cable plasticiser specification often overlooked by formulators: residual alcohol, catalyst traces, or ionic contaminants from inadequate purification reduce electrical insulation performance, causing increased leakage current and premature dielectric failure in medium-voltage applications (6 kV, 10 kV grades). TM810's volume resistivity, verified per KLJTM/IEC 60811, directly supports compound qualification for these cable grades.
For EV/HEV wiring harnesses (SAE J1678, ISO 6722, continuous 105°C service), TM810-based PVC compounds provide a cost-effective solution for battery cable insulation, charging cable jackets, and under-hood wiring where TM810's low migration and oil resistance prevent plasticiser extraction by engine fluids and battery electrolyte components.
2. Automotive Interior PVC - Anti-Fogging, IMDS Phthalate-Free, RoHS Compliant
Automotive interior PVC - instrument panel skins, door panel trim, seat surfaces, centre consoles - experiences solar loading reaching 90–100°C surface temperature in hot climates while demanding flexibility at −30 to −40°C in winter. Plasticiser migration causes fogging (volatile plasticiser condensing on interior glass) and surface brittleness. TM810's low volatility (flash point 252°C, volatile loss 0.08% at 130°C/3h) provides measurably better anti-fogging performance than phthalate plasticisers in automotive interior testing, across both the −40°C to +90°C passenger compartment temperature range and UV exposure conditions.
TM810's non-phthalate identity directly satisfies IMDS phthalate-free reporting requirements under the EU End-of-Life Vehicle (ELV) Directive, and its RoHS compliance eliminates the restricted substance concern for automotive electronics embedded in interior assemblies. Sinolook provides a non-phthalate product letter specifically for IMDS/ELV Directive automotive material documentation, and a RoHS Declaration of Conformity (DoC) for component-level RoHS filings.
3. Medical-Grade PVC - Steam Sterilisation Compatible DEHP Alternative
Medical PVC devices requiring steam sterilisation (autoclave at 121°C/15 min or 134°C/3 min) must survive high temperature, steam pressure, and aqueous exposure without surface plasticiser exudation. TM810's volatile loss ≤0.10% at 130°C/3h directly validates stability through the 121°C autoclave cycle - testing at 130°C covers the 121°C exposure with margin for the 134°C rapid cycle. Low extractability in aqueous and saline media, attributable to ~570 g/mol MW reducing diffusion rate through the PVC matrix, supports biocompatibility qualification for blood contact and infusion set applications.
Compared to DEHP-plasticised medical PVC - subject to EU MDR Article 1(8) restricted substance declaration requirements for Class IIa and above devices containing DEHP above 0.1% - TM810's non-Repr. 1B, non-REACH-restricted status eliminates the obligation to justify DEHP content in device technical documentation and clinical evaluation reports. Applications: infusion sets, blood collection bags and tubing, dialysis blood lines, urinary catheters, nasogastric tubing. Medical-grade COA with Pt-Co ≤30, heavy metals, and batch extraction screening available on request.
4. High-Temperature Synthetic Lubricants, Heat-Resistant PVC & Specialty Resins
High-temperature synthetic lubricant base oil: TM810's operating range of −46°C to ~250°C (defined by pour point and flash point) covers a wider thermal span than most mineral oils and competing synthetic esters. In high-temperature chain lubricants, high-speed bearing greases, and air compressor oils, TM810's pour point of −46°C is significantly lower than TOPM (−27°C) - making it the preferred trimellitate ester for cold-start performance at −40°C. TM810 is miscible with PAO and Group III/II mineral oils in all proportions for semi-synthetic blends. A proven blending formula for high-temperature chain oil needing both cold-start and high-temperature performance: TOPM 60–70% (base, high-temperature stability) + TM810 20–30% (lowers blended pour point below −40°C) + PAO 10–20% (oxidative stability, VI).
Heat-resistant PVC seals, sheets & artificial leather: Non-phthalate plasticiser in industrial seals, gaskets, conveyor belts, and automotive artificial leather. Non-phthalate status satisfies RoHS and ELV requirements; flexibility at −46°C maintains seal performance in cold-climate outdoor service.
PVB & specialty resin plasticisation: Permanent plasticiser for polyvinyl butyral (PVB) interlayer films in architectural and automotive safety glass, specialty PU and acrylic resin systems, heat-resistant coatings and adhesives requiring high thermal stability, low volatility, and low migration at elevated service temperatures.
TM810 vs TOTM vs TOPM vs DEHP - Trimellitate Plasticiser Selection
| Property | DEHP / DOP 117-81-7 |
TOTM 3319-31-1 |
TM810 68515-42-4 |
TOPM 3126-80-5 |
|---|---|---|---|---|
| Ester type | Di-ester phthalate | Tri-ester trimellitate (branched C8) | Tri-ester trimellitate (linear C8+C10) | Tetra-ester pyromellitate |
| Avg. MW (g/mol) | ~391 | ~547 | ~570 (higher than TOTM) | 703 |
| Flash Point (°C) | ~185 | ~245 | ≥240 (actual 252) ✓ | ≥265 (actual 270) ✓✓ |
| Pour Point (°C) | ~−55 | ~−39 ⚠ (marginal vs −40°C) | ≤−40 (actual −46) ✓✓ best trimellitate | ≤−18 (actual −27) |
| Volatile Loss 130°C/3h | - | ~0.15–0.20% ⚠ | ≤0.10% (actual 0.08%) ✓ lowest | ≤1.5% @ 250°C/1h |
| Volume Resistivity | ~1×10¹¹ Ω·cm | ~5×10¹¹ Ω·cm | ≥5×10¹¹ (actual 7.0×10¹¹) ✓ | - |
| Low-temp flex −40°C | Good | Marginal ⚠ | Excellent ✓✓ | Adequate |
| EU Repr. 1B | Repr. 1B ⚠ | Not classified ✓ | Not classified ✓ | Not classified ✓ |
| REACH / RoHS | Annex XIV + RoHS ⚠ | OK ✓ | Non-phthalate · RoHS DoC ✓ | OK ✓ |
| Key strength | Lowest cost | Balanced performance | Best low-temp + cable ✓✓ | Best high-temp stability ✓✓ |
Regulatory Status - Non-Phthalate · No CMR · RoHS Compliant · Non-HAP
Storage, Handling & Safety
Storage
5–30°C in sealed metal drums or IBC tanks. Remains pumpable above 0°C (pour point −46°C). Standard combustible liquid storage; no explosion-proof electrical required. Fire-fighting: dry powder or CO₂. Keep drums sealed - TM810 absorbs moisture slowly; moisture increases acid value. Segregate from strong oxidisers, strong acids, bases; safe distance ≥10 m from heat sources.
Shelf life: 12 months sealed at 5–30°C. Retest acid value and colour if stored >9 months. Nitrogen blanket recommended for long-term storage (>6 months) to prevent oxidative colour development. Max 3-layer drum stacking; IBC single-layer only.
PPE & Handling
GHS hazards: Mild irritant. No flammability hazard at ambient. No CMR. No phthalate hazard. General ventilation adequate at ambient; local exhaust for heated mixing above 150°C.
Gloves: Nitrile ≥0.1 mm; safety goggles for routine handling. Spill: High viscosity (497 cP) - slow spreading. Absorb with dry sand or vermiculite; dispose as non-hazardous industrial ester waste. No reproductive health risk assessment required. Full occupational data: GESTIS CAS 68515-42-4 ↗
Frequently Asked Questions about TM810
Q: What is the difference between TM810 and TOTM - are they the same product?
TM810 and TOTM are related but distinct substances - both TMA-derived trimellitate esters, but with different alcohols. TOTM uses 2-ethylhexanol (branched C8), CAS 3319-31-1; TM810 uses a blend of n-octanol (linear C8) and n-decanol (linear C10), CAS 68515-42-4. Measurable differences: TM810 pour point −46°C vs TOTM ~−39°C, and volatile loss 0.08% vs ~0.15–0.20% at 130°C/3h. For most applications (105°C cable, automotive interior PVC, lubricant base oil), TM810 and TOTM are functionally interchangeable, with TM810 preferred when the lowest pour point and cold-temperature flexibility are priorities. Always use CAS 68515-42-4 for TM810 in REACH filings, IMDS entries, and procurement documents - not CAS 3319-31-1.
Q: Does TM810 comply with EU RoHS Directive restrictions on phthalates?
Yes - TM810 is fully RoHS 2011/65/EU compliant, including the 2019 phthalate amendments. TM810 is a trimellitate ester (ester of benzene-1,2,4-tricarboxylic acid), structurally unrelated to phthalate esters (esters of benzene-1,2-dicarboxylic acid / phthalic acid). The RoHS phthalate restriction (DEHP, BBP, DBP, DIBP ≤0.1% by weight) applies specifically to those four phthalates and other restricted substances - not to trimellitate esters. Sinolook provides a RoHS Declaration of Conformity explicitly confirming TM810's non-phthalate identity for cables, connectors, automotive components, and electronic equipment covered by the Directive.
Q: Why does TM810 achieve −46°C pour point - lower than TOTM's ~−39°C?
TM810's −46°C pour point vs TOTM's ~−39°C results from the difference in alcohol chain structure. TOTM's 2-ethylhexyl (branched C8) chains have restricted rotational freedom from the branch point, limiting the conformational mobility that allows low-temperature pumpability. TM810's n-decyl (linear C10) chains are longer and have greater conformational flexibility - they adopt extended conformations that pack less efficiently and require lower temperatures to arrest molecular motion. The two additional methylene units of the C10 chain contribute an internal plasticising effect. This 7°C pour point advantage is directly significant for cable installations in Northern Europe, Canada, Russia, and northern China where the IEC 60502 cold-bend test qualification at −40°C is required.
Q: Can TM810 be mixed with TOPM or PAO in lubricant formulations?
Yes - TM810 and TOPM are mutually miscible in all proportions, as are TM810 with PAO and Group II/III mineral oils. Blending TM810 with TOPM allows interpolation between TM810's superior cold-start performance (pour point −46°C) and TOPM's superior high-temperature stability (flash point 270°C, lowest carbon deposition at 260°C/3h). A proven chain oil formula requiring both cold-start and maximum chain cleanliness at 250°C: TOPM 60–70% + TM810 20–30% + PAO 10–20% - giving blended pour point below −40°C while retaining most of TOPM's high-temperature advantage. TM810's three ester groups also help solubilise anti-wear and antioxidant additive packages in PAO-rich formulations. Sinolook provides blending guidance and formulation optimisation support for TM810/TOPM/PAO combination lubricants.
Authoritative Technical & Regulatory References
Use CAS 68515-42-4 (EC 271-090-9) for TM810 in all regulatory filings, IMDS entries, and procurement documents - not CAS 3319-31-1 (TOTM, a separate substance).
ECHA substance page for tri(octyl,decyl) trimellitate: no CMR classification, no SVHC listing, REACH registration status, no Annex XIV/XVII restrictions.
NCBI PubChem record for CAS 68515-42-4: IUPAC name, mixed C8/C10 isomer composition, GHS classification, and physicochemical data for TM810.
EPA CompTox Dashboard for CAS 68515-42-4: TSCA inventory listing, non-HAP confirmation, and available environmental data.
ECHA substance page for TOTM - the branched C8 trimellitate reference for structural and performance comparison with TM810's linear C8/C10 mixed ester. Note: separate substance from TM810 (CAS 68515-42-4).
ECHA substance page for DEHP - confirming Repr. 1B (H360FD), REACH Annex XIV listing, and RoHS phthalate restriction that TM810 avoids as a non-phthalate trimellitate.
IFA GESTIS database for CAS 68515-42-4: occupational safety classification, physicochemical properties, and health hazard summary confirming TM810's low-hazard handling profile.
Buy TM810 · Non-Phthalate C8/C10 Trimellitate · 105°C Cable Grade · CAS 68515-42-4 · China Manufacturer
Request TM810 Price, Qualification Sample & Compliance Documentation
Sinolook supplies TM810 (CAS 68515-42-4) with full multi-standard COA (ASTM D1045/D92/D97/KF): pour point ≤−40°C (actual −46°C), volatile loss ≤0.10% @ 130°C/3h, volume resistivity ≥5×10¹¹ Ω·cm. Complete compliance package: RoHS DoC, REACH no-restriction letter, non-phthalate IMDS letter, non-HAP declaration. Qualification samples 0.5–5 kg. Volumes from 200 kg to ISO tanks. Lead time 7–15 business days. 24-hour response.
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